Pressure-induced transitions in ferroelectric single-crystal PbZr0.54Ti0.46O3. (26th October 2018)

• Record Type: Journal Article
• Authors: Ahart, Muhtar; Somayazulu, Maddury; Popov, Dmitry; Xie, Yujuan; Long, Xifa; Ye, Zuo-Guang; Cohen, R. E.; Hemley, Russell J.
• Is Part Of: Ferroelectrics. Volume 535(2018)
• Page Start: 106
• Page End: 113
• Publication Date: 2018-10-26
• Subjects: PZT single crystal -- structural transitions -- high-pressure -- Raman scattering -- x-ray diffraction; Ferroelectricity -- Periodicals; Ferroelectric crystals -- Periodicals; 537
• DOI: 10.1080/00150193.2018.1474652
• Languages: English
• ISSNs: 0015-0193

Abstract

Abstract: Pressure-induced phase transitions in single-crystal PbZr0.54 Ti0.46 O3 are investigated with high-pressure Raman scattering and x-ray single crystal and powder diffraction. The appearance of a Raman peak near 380 cm −1 indicates a structural transition at 3 GPa. A second transition, driven by an soft optical phonon, occurs at 9 GPa. A third transition occurs above 27 GPa, accompanied by a large changes in the Raman spectrum and splitting of the (pseudo-cubic) (111) and (220) diffraction lines. We identify the transitions as a monoclinic ( C m) to rhombohedral ( R 3m) transition at 3 GPa, followed by a rhombohedral ( R 3m) to rhombohedral ( R -3c) transition at 9 GPa, and a further symmetry-lowering transition at 27 GPa.