Iron‐Catalyzed Minisci Type Acetylation of N‐Heteroarenes Mediated by CH(OEt)3/TBHP. Issue 8 (14th February 2019)

• Record Type: Journal Article
• Authors: Srinivasulu, A.; Shantharjun, B.; Vani, D.; Ashalu, K. Chinna; Mohd, A.; Wencel‐Delord, J.; Colobert, F.; Reddy, K. Rajender
• Is Part Of: European journal of organic chemistry. Issue 8(2019)
• Page Start: 1815
• Page End: 1819
• Publication Date: 2019-02-14
• Subjects: Acetylation -- Iron catalyst -- N‐heteroarenes -- Triethylorthoformate -- TBHP; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.201900033
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract : Iron‐catalyzed acetylation of electron deficient N‐heteroarenes has been reported using triethylorthoformate as robust and inexpensive acetyl source. This new method is successfully applied for the acetylation of quinolines, isoquinoline, quinoxalines, arylpyridines, bipyridines, and benzothiazole. Abstract : Iron catalysed acetylation of electron deficient N‐heteroarenes has been reported using triethylorthoformateas robust and inexpensive acetyl source. This new method is successfully applied for the acetylation of quinolines, isoquinoline, quinoxalines, arylpyridines, bipyridines, and benzothiazole.