Concise synthesis of the core structure of madreporanone by Rh-catalyzed [3+2] cycloaddition. Issue 12 (22nd March 2019)
- Record Type:
- Journal Article
- Title:
- Concise synthesis of the core structure of madreporanone by Rh-catalyzed [3+2] cycloaddition. Issue 12 (22nd March 2019)
- Main Title:
- Concise synthesis of the core structure of madreporanone by Rh-catalyzed [3+2] cycloaddition
- Authors:
- Long, Rong
Yang, Zhen - Abstract:
- Abstract: A model study toward total synthesis of madreporanone, a novel diterpene isolated from Azorella madreporica, was investigated. The [3.3.0] bicyclic core of madreporanone bearing a cis -configured isopropyl group and two vicinal quaternary carbon centers was stereoselectively constructed via an intramolecular Rh-catalyzed [3 + 2] cycloaddition in a single step. Graphical abstract: Image 1
- Is Part Of:
- Tetrahedron. Volume 75:Issue 12(2019)
- Journal:
- Tetrahedron
- Issue:
- Volume 75:Issue 12(2019)
- Issue Display:
- Volume 75, Issue 12 (2019)
- Year:
- 2019
- Volume:
- 75
- Issue:
- 12
- Issue Sort Value:
- 2019-0075-0012-0000
- Page Start:
- 1746
- Page End:
- 1750
- Publication Date:
- 2019-03-22
- Subjects:
- Madreporanone -- Vicinal quaternary carbon centers -- Stereoselective -- Rh-catalyzed [3+2] cycloaddition
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2018.11.047 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 9639.xml