Copper-catalyzed synthesis of 3-allyl-2-aminoindoles from 3-diazoindolin-2-imines and allyltrimethylsilane. Issue 12 (22nd March 2019)
- Record Type:
- Journal Article
- Title:
- Copper-catalyzed synthesis of 3-allyl-2-aminoindoles from 3-diazoindolin-2-imines and allyltrimethylsilane. Issue 12 (22nd March 2019)
- Main Title:
- Copper-catalyzed synthesis of 3-allyl-2-aminoindoles from 3-diazoindolin-2-imines and allyltrimethylsilane
- Authors:
- Lang, Bo
Zhou, Yuxuan
Lu, Ping
Wang, Yanguang - Abstract:
- Abstract: A novel and facile approach to 3-allyl-2-aminoindoles via the copper-catalyzed reaction of 3-diazoindolin-2-imines with allyltrimethylsilane is described. The domino reaction proceeds efficiently in one-pot and shows broad substrate scope with respect to the diazo substrates. Furthermore, the synthesized 3-allyl-2-aminoindoles can be conveniently transformed into 3-allyl-3-hydroxylindolin-2-imines and 3-allyl-3-fluoroindolin-2-imines. Graphical abstract: Image 1
- Is Part Of:
- Tetrahedron. Volume 75:Issue 12(2019)
- Journal:
- Tetrahedron
- Issue:
- Volume 75:Issue 12(2019)
- Issue Display:
- Volume 75, Issue 12 (2019)
- Year:
- 2019
- Volume:
- 75
- Issue:
- 12
- Issue Sort Value:
- 2019-0075-0012-0000
- Page Start:
- 1597
- Page End:
- 1604
- Publication Date:
- 2019-03-22
- Subjects:
- Copper catalysis -- Metal carbenes -- Diazo compounds -- 3-Allyl-2-aminoindoles
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2018.11.032 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 9626.xml