A convenient synthesis of 4, 6-dimethyl-2-(methylsulfonyl)pyrimidine. (1st December 2013)
- Record Type:
- Journal Article
- Title:
- A convenient synthesis of 4, 6-dimethyl-2-(methylsulfonyl)pyrimidine. (1st December 2013)
- Main Title:
- A convenient synthesis of 4, 6-dimethyl-2-(methylsulfonyl)pyrimidine
- Authors:
- Xu, Defeng
Zhu, Zhiling
Wang, Ziqiao - Abstract:
- A convenient and efficient three-step synthesis of 4, 6-dimethyl-2-(methylsulfonyl) pyrimidine can be achieved by cyclocondensation of acetylacetone and thiourea in the presence of hydrochloric acid to yield 4, 6-dimethyl-1-mercaptopyrimidine, methylation with dimethyl carbonate and tetrabutylammonium bromide to give 4, 6-dimethyl-2-methyl thiopyrimidine, and oxidation with hydrogen peroxide, sodium tungstate and tetrabutylammonium bromide to afford the title compound in an overall yield of 75%.
- Is Part Of:
- Journal of chemical research. Volume 37:Number 12(2013)
- Journal:
- Journal of chemical research
- Issue:
- Volume 37:Number 12(2013)
- Issue Display:
- Volume 37, Issue 12 (2013)
- Year:
- 2013
- Volume:
- 37
- Issue:
- 12
- Issue Sort Value:
- 2013-0037-0012-0000
- Page Start:
- 720
- Page End:
- 721
- Publication Date:
- 2013-12-01
- Subjects:
- Chemistry -- Research -- Periodicals
Chemistry -- Periodicals
540.5 - Journal URLs:
- http://stl.publisher.ingentaconnect.com/content/stl/jcr ↗
https://journals.sagepub.com/home/chl ↗
http://www.sciencereviews2000.co.uk/ ↗ - DOI:
- 10.3184/174751913X13824447710542 ↗
- Languages:
- English
- ISSNs:
- 1747-5198
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 9610.xml