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Sodium perborate/trifluoroacetic anhydride oxidation of ketones using poly(iodostyrene) as the catalyst: a direct route to α-hydroxy ketones. (1st January 2014)
Record Type:
Journal Article
Title:
Sodium perborate/trifluoroacetic anhydride oxidation of ketones using poly(iodostyrene) as the catalyst: a direct route to α-hydroxy ketones. (1st January 2014)
Main Title:
Sodium perborate/trifluoroacetic anhydride oxidation of ketones using poly(iodostyrene) as the catalyst: a direct route to α-hydroxy ketones
Exposure of ketones to NaBO3.4H2O/(CF3CO)2O in the presence of a catalytic amount of poly(iodostyrene) afforded α-hydroxy ketones in good yield, with potential applications in the construction of α-hydroxy ketone subunit in natural product synthesis.