Rational Design of Cyclopenta[2, 1‐b;3, 4‐b′]dithiophene‐bridged Hole Transporting Materials for Highly Efficient and Stable Perovskite Solar Cells. Issue 2 (15th January 2019)

• Record Type: Journal Article
• Authors: Lin, Yan‐Duo; Lee, Kun‐Mu; Ke, Bo‐Yu; Chen, Kai‐Shiang; Cheng, Hao‐Chien; Lin, Wei‐Juih; Chang, Sheng Hsiung; Wu, Chun‐Guey; Kuo, Ming‐Chung; Chung, Hsin‐Cheng; Chou, Chien‐Chun; Chen, Heng‐Yu; Liau, Kang‐Ling; Chow, Tahsin J.; Sun, Shih‐Sheng
• Is Part Of: Energy technology. Volume 7:Issue 2(2019:Feb.)
• Page Start: 307
• Page End: 316
• Publication Date: 2019-01-15
• Subjects: perovskite solar cell -- hole transporting materials -- cyclopenta[2, 1-b;3, 4-b′]dithiophene -- long-term stability; Energy development -- Periodicals; Power resources -- Periodicals; 333.79
• DOI: 10.1002/ente.201800939
• Languages: English
• ISSNs: 2194-4288

Abstract

Abstract: A series of small‐molecule‐based hole‐transporting materials (HTMs) featuring a 4 H ‐cyclopenta[2, 1‐b : 3, 4‐b′]dithiophene as the central core with triphenylamine‐ and carbazole‐based side groups was synthesized and evaluated for perovskite solar cells. The correlations of the chemical structure of the HTMs on the photovoltaic performance were explored through different combinations of the central π‐bridge moieties. The optical and electrochemical properties, energy levels, and hole mobility were systematically investigated, revealing the significant influence of the central core planarity and packing structure on their photovoltaic performance. The optimized device based onCT1 exhibited a PCE (power conversion efficiency) of 17.71 % with a device architecture of FTO/TiO2 compact layer/TiO2 mesoporous/CH3 NH3 PbI3 /HTM/MoO3 /Ag, which was found to be on par with that of a cell fabricated based on state‐of‐the‐art spiro‐OMeTAD (16.97 %) as HTM. Moreover, stability assessment showed an improved stability for CPDT‐based HTMs in comparison with spiro‐OMeTAD over 1300 h. Abstract : Four HTMs based on cyclopenta[2, 1‐b;3, 4‐b′]dithiophene core are designed and applied for lead perovskite (MAPbI3 ) solar cells. PSCs based onCT1 as HTM afford an impressive power conversion efficiency of 17.71 %. The devices based on theCT1 presented significantly higher stability than the device based on spiro‐OMeTAD.