Dehydrogenative Sn–E (E = S, Se) bond formation catalyzed by an iron complex. Issue 5 (4th December 2018)

• Record Type: Journal Article
• Authors: Itazaki, Masumi; Ogawa, Yudai; Nakamura, Wataru; Nakazawa, Hiroshi
• Is Part Of: Heteroatom chemistry. Volume 29:Issue 5/6(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-12-04
• Subjects: dehydrogenative coupling -- hydrostannane -- iron -- selenol -- thiol; Heterocyclic chemistry -- Periodicals; 547.59
• DOI: 10.1002/hc.21461
• Languages: English
• ISSNs: 1042-7163

Abstract

Abstract: Iron complex‐catalyzed dehydrogenative Sn–E (E = S, Se) bond formation of hydrostannane with thiol and selenol was achieved. All new compounds were fully characterized using 1 H, 13 C{ 1 H}, 77 Se{ 1 H}, and 119 Sn{ 1 H} NMR measurements and elemental analyses. The structure of 1, 1′‐(1, 3‐dithia‐2, 2‐dibutylstanyl)‐[3]ferrocenophane was confirmed by single‐crystal X‐ray diffraction.