Thermodynamic and spectroscopic study of molecular interactions between ethanol and isomeric cresols. (May 2019)

• Record Type: Journal Article
• Authors: Raveendra, M.; Bhanuprakash, P.; Rao, Y. Subba; Siva Kumar, K.; Dayananda Reddy, K.
• Is Part Of: Journal of chemical thermodynamics. Volume 132(2019)
• Page Start: 93
• Page End: 104
• Publication Date: 2019-05
• Subjects: FT-IR -- Binary mixture -- Excess properties -- Partial molar volume -- Hydrogen bonding; Thermodynamics -- Periodicals; Thermochemistry -- Periodicals; Thermodynamique -- Périodiques; Thermochimie -- Périodiques; Thermochemistry; Thermodynamics; Periodicals; 541.369
• DOI: 10.1016/j.jct.2018.12.039
• Languages: English
• ISSNs: 0021-9614

Abstract

Graphical abstract: Highlights: Excess properties were studied for the binary mixtures of ethanol with isomeric cresols. V E and κS E data were correlated with Redlich-Kister and Hwang equations. Intermolecular H-bonding in the binary mixtures was studied by FT-IR Spectroscopy. Explained the effect of position of –OH group on the excess properties of mixtures. Abstract: The densities ( ρ ) of binary liquid mixtures of ethanol with o -cresol, m -cresol and p -cresol have been analysis at temperatures T = (303.15, 308.15, 313.15 and 318.15) K and speeds of sound ( u ) of the same liquid mixtures were measured at T = (303.15 and 313.15) K. The experimental data were used to compute several thermodynamic properties, namely, excess volume ( V E ), excess isentropic compressibilities ( κs E ) and the volumetric properties like excess partial molar volume ( V ¯ m, 1 E, V ¯ m, 2 E ), partial molar volume ( V ¯ m, 1 0, V ¯ m, 2 0 ), excess partial molar volume ( V ¯ m, 1 0 E, V ¯ m, 2 0 E ) at infinite dilutions. Moreover, the measured speed of sound was estimated in terms of Jacobson's free length theory (FLT) and Schaff's collision factor theory (CFT) to check the capability of theoretical models. The excess functions ( V E, κs E ) were fitted and correlated with Redlich-Kister & Hwang equations. The results were discussed in terms of intermolecular H-bonding interactions between ethanol with isomeric cresols and confirmed by FT-IR Spectral studies.