Mg–Mg-bonded compounds with N, N′-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands. Issue 7 (25th January 2019)

• Record Type: Journal Article
• Authors: Ma, Meimei; Wang, Huanhuan; Wang, Juju; Shen, Lingyi; Zhao, Yanxia; Xu, Wen-Hua; Wu, Biao; Yang, Xiao-Juan
• Is Part Of: Dalton transactions. Volume 48:Issue 7(2019)
• Page Start: 2295
• Page End: 2299
• Publication Date: 2019-01-25
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9dt00028c
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Two Mg–Mg-bonded compounds were synthesized by using phenanthrene-diimine and o -phenylenediamine ligands; their UV-Vis and fluorescence spectra and reactivity were studied. Abstract : Two Mg–Mg-bonded compounds were synthesized by using the ligands N, N ′-bis(dipp)-phenanthrene-9, 10-diimine (L 2 ) and N, N ′-bis(dipp)- o -phenylenediamine (H2 L 3 ; dipp = 2, 6-diisopropylphenyl). These new Mg(i ) species were characterized by X-ray diffraction, NMR, UV-Vis and fluorescence spectroscopy, and DFT computations. Their reactions with unsaturated organic molecules were examined.