Coquandite, Sb6+xO8+x(SO4)(OH)x·(H2O)1–x (x = 0.3), from the Cetine mine, Tuscany, Italy: crystal structure and revision of the chemical formula. (August 2014)

• Record Type: Journal Article
• Authors: Bindi, L.; Biagioni, C.; Ceccantini, L.; Batoni, M.; Menchetti, S.
• Is Part Of: Mineralogical magazine. Volume 78:Number 4(2014:Aug.)
• Page Start: 871
• Page End: 888
• Publication Date: 2014-08
• Subjects: coquandite, -- Sb-sulfates, -- structure solution, -- crystal-structure refinement, -- Cetine mine; Mineralogy -- Periodicals; Mineralogy -- Great Britain -- Periodicals; 549.05
• DOI: 10.1180/minmag.2014.078.4.08
• Languages: English
• ISSNs: 0026-461X

Abstract

Abstract: The crystal structure of the mineral coquandite, a rare Sb oxy-sulfate hydrate, was solved using intensity data collected from a crystal from the Cetine mine, Tuscany, Italy. This study revealed that the structure is triclinic, space group P, with a = 11.4292(5), b = 29.772(1), c = 11.2989(5) Å, α = 91.152(3), β = 119.266(4), γ = 92.624(3)° and V = 3346.4(2) Å 3 . The refinement of an anisotropic model led to an R index of 0.0347 for 21, 061 independent reflections. Thirty-two Sb sites, five S sites and 67 oxygen sites occur in the crystal structure of coquandite. Sb atoms display the characteristic SbO3 E and SbO4 E coordinations whereas S fills (SO4 ) tetrahedral groups. These atoms are arranged in five symmetry-independent layers perpendicular tob *. Four of them and their centrosymmetrical counterparts form complex modules stacked alongb * and bonded through two Sb atoms and H bonds. The complex H bonding system in the structure is discussed. On the basis of information gained from this characterization, the crystal-chemical formula was revised according to the structural results, yielding Sb6+ x O8+ x (SO4 )(OH) x ·(H2 O)1– x ( Z = 10) with x = 0.3 instead of Sb6 O8 (SO4 )·H2 O ( Z = 12) as reported previously. A recalculation of the chemical data listed in the scientific literature for coquandite according to the structural results obtained here leads to a satisfactory agreement.