Cu-catalyzed regio- and stereoselective sulfonylation of multi-substituted allenes. Issue 9 (1st March 2019)
- Record Type:
- Journal Article
- Title:
- Cu-catalyzed regio- and stereoselective sulfonylation of multi-substituted allenes. Issue 9 (1st March 2019)
- Main Title:
- Cu-catalyzed regio- and stereoselective sulfonylation of multi-substituted allenes
- Authors:
- Arai, Shigeru
Matsumoto, Koki
Nishida, Atsushi - Abstract:
- Abstract: Regio- and stereoselective sulfonylation of allenes under Cu catalysis is described. Allenyl sp carbons exclusively react with TsCN to give the corresponding alkenyl sulfones. The reaction is initiated by addition of tosyl radical to form benzyl radical intermediates, which determines the reaction pathway. The structure of the products is highly dependent on the substituents on allenes. Graphical abstract: Image 1
- Is Part Of:
- Tetrahedron. Volume 75:Issue 9(2019)
- Journal:
- Tetrahedron
- Issue:
- Volume 75:Issue 9(2019)
- Issue Display:
- Volume 75, Issue 9 (2019)
- Year:
- 2019
- Volume:
- 75
- Issue:
- 9
- Issue Sort Value:
- 2019-0075-0009-0000
- Page Start:
- 1145
- Page End:
- 1148
- Publication Date:
- 2019-03-01
- Subjects:
- Allenes -- Cu -- Catalysis -- Regioselective -- Stereoselective
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2018.12.031 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 9509.xml