Crystal structure and improved thermoelectric performance of iron stabilized cubic Cu3SbS3 compound. Issue 2 (18th December 2018)

• Record Type: Journal Article
• Authors: Du, Baoli; Zhang, Ruizhi; Liu, Ming; Chen, Kan; Zhang, Hangfeng; Reece, Michael J.
• Is Part Of: Journal of materials chemistry. Volume 7:Issue 2(2019)
• Page Start: 394
• Page End: 404
• Publication Date: 2018-12-18
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c8tc05301d
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : The high performance of the iron-stabilized cubic structure of Cu3 SbS3 makes it a strong candidate for thermoelectric application. Abstract : Cu3 SbS3 is a copper-based thermoelectric (TE) sulfide with strong vibrational anharmonicity, and it is a member of the Cu–Sb–Se system with lone pair electrons on the Sb sites and three-coordinated Cu ions exhibiting a large vibrational amplitude. However, a phase transition within the working temperature range will inevitably deteriorate the joint between the TE legs and substrates. Here, we successfully stabilized its less-known cubic structure by incorporating Fe atoms into Cu3 SbS3 . Phase structure analysis showed that the cubic structure is similar to that of the well-known tetrahedrite (Cu3 SbS3.25 ), with the S atom at the centre of the unit cell missing. The thermodynamic stability and phase evolution of the materials were studied up to 623 K in both air and Ar atmospheres. The improved TE performance and the electron band structure were also identified and correlated. All results indicated that cubic Cu3 SbS3 cannot be regarded as a derivative of S-deficient tetrahedrite, and theoretical modeling revealed its unique electron band structure. Benefiting from the low thermal conductivity, the Cu3 Fe0.1 Sb0.9 S3 sample shows a higher zT than tetrahedrite in the whole testing temperature range, with a maximum of 0.70 being achieved around 550–625 K. Our results firmly demonstrate the possibility of stabilising the cubic structure of Cu3 SbS3 by Fe incorporation and highlight it as a strong candidate for high performance TE materials.