Dual Gold‐Catalyzed Cycloaromatization of Unconjugated (E)‐Enediynes. (16th January 2019)
- Record Type:
- Journal Article
- Title:
- Dual Gold‐Catalyzed Cycloaromatization of Unconjugated (E)‐Enediynes. (16th January 2019)
- Main Title:
- Dual Gold‐Catalyzed Cycloaromatization of Unconjugated (E)‐Enediynes
- Authors:
- Zamani, Farzad
Babaahmadi, Rasool
Yates, Brian F.
Gardiner, Michael G.
Ariafard, Alireza
Pyne, Stephen G.
Hyland, Christopher J. T. - Abstract:
- Abstract: A synthesis of unconjugated ( E )‐enediynes from allenyl amino alcohols is reported and their gold‐catalyzed cascade cycloaromatization to a broad range of enantioenriched substituted isoindolinones has been developed. Experimental and computational studies support the reaction proceeding via a dual‐gold σ, π‐activation mode, involving a key gold‐vinylidene‐ and allenyl‐gold‐containing intermediate.
- Is Part Of:
- Angewandte Chemie. Volume 131:Number 7(2019)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 131:Number 7(2019)
- Issue Display:
- Volume 131, Issue 7 (2019)
- Year:
- 2019
- Volume:
- 131
- Issue:
- 7
- Issue Sort Value:
- 2019-0131-0007-0000
- Page Start:
- 2136
- Page End:
- 2141
- Publication Date:
- 2019-01-16
- Subjects:
- Cycloaromatisierungen -- Duale Gold-Katalyse -- Endiine -- Isoindolinone
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201810794 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 9496.xml