3D Porous Heterometallic Coordination Polymer for the Detection of Nitroaromatic Explosives and Inhibiting Human Cancer Cells Growth. Issue 2 (16th September 2018)

• Record Type: Journal Article
• Authors: Wang, Yu; Li, Chen
• Is Part Of: Zeitschrift für anorganische und allgemeine Chemie. Volume 645:Issue 2(2019)
• Page Start: 87
• Page End: 91
• Publication Date: 2018-09-16
• Subjects: Heterometallic compound -- Solvothermal synthesis -- Porous framework -- Luminescence sensing -- Cadmium -- Strontium; Chemistry, Inorganic -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1002/zaac.201800280
• Languages: English
• ISSNs: 0044-2313

Abstract

Abstract : A new heterometallic coordination polymer, namely [Cd2 Sr(bdc)3 (H2 O)2 ] n (1 ) (H2 bdc = terephthalic acid), was synthesized via the solvothermal reaction of Cd(NO3 )2, Sr(NO3 )2, and H2 bdc. The X‐ray structural analysis reveals that compound1 is a 3D framework based on 1D rod‐shaped heterometallic metal‐carboxylate chains as building subunits. Viewing along the crystallographic c axis, there exist large 1D rhombic channels with effective dimensions of ca. 10.0 × 18.6 Å 2 . Moreover, compound1 emits intense luminescence at room temperature. The investigations of luminescence indicated that compound1 can be served as a luminescence probe for the detection of nitroaromatic explosives. Furthermore, the anticancer activity of1 was evaluated against three human cancer cells MCF‐7, MDA‐MB‐231, and MDA‐MB‐435S via the MTT assay. Abstract :