Teaching c-phosphanylimines the titanaaziridine coordination mode. Issue 6 (21st December 2018)

• Record Type: Journal Article
• Authors: Fischer, Malte; Steinert, Henning; Schmidtmann, Marc; Beckhaus, Ruediger
• Is Part Of: Dalton transactions. Volume 48:Issue 6(2019)
• Page Start: 1936
• Page End: 1940
• Publication Date: 2018-12-21
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c8dt04918a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The employment of a c -phosphanylimine for the synthesis of a novel titanaaziridine with an intramolecular phosphine donor side is reported, thus teaching the c -phosphanylimine a new coordination mode. Abstract : The c -phosphanylimineL1 was employed for the synthesis of the novel titanaaziridine1 with an intramolecular phosphine donor side following a reductive complexation route. This coordination mode is new for c -phosphanylimines and compound1 is the first group 4 complex featuring a c -phosphanylimine ligand.