Mechanisms of Bisphosphine Iron-Catalyzed C(SP2)-C(SP3) Cross-Coupling Reactions: Inner-Sphere or Outer-Sphere Arylation?. Issue 6 (2nd November 2018)
- Record Type:
- Journal Article
- Title:
- Mechanisms of Bisphosphine Iron-Catalyzed C(SP2)-C(SP3) Cross-Coupling Reactions: Inner-Sphere or Outer-Sphere Arylation?. Issue 6 (2nd November 2018)
- Main Title:
- Mechanisms of Bisphosphine Iron-Catalyzed C(SP2)-C(SP3) Cross-Coupling Reactions: Inner-Sphere or Outer-Sphere Arylation?
- Authors:
- Liu, Lei
Lee, Wes
Yuan, Mingbin
Gutierrez, Osvaldo - Abstract:
- Abstract : In this comment, we present recent insights into the mechanism of bisphosphine-iron catalyzed C(sp 2 )-C(sp 3 ) cross-coupling reactions (CCRs) with the focus on the nature of the C-C bond formation event (inner-sphere versus outer-sphere) as revealed by quantum mechanical calculations from our group and others. Implications for reaction and catalyst design principles are discussed. Graphical Abstract:
- Is Part Of:
- Comments on inorganic chemistry. Volume 38:Issue 6(2018)
- Journal:
- Comments on inorganic chemistry
- Issue:
- Volume 38:Issue 6(2018)
- Issue Display:
- Volume 38, Issue 6 (2018)
- Year:
- 2018
- Volume:
- 38
- Issue:
- 6
- Issue Sort Value:
- 2018-0038-0006-0000
- Page Start:
- 210
- Page End:
- 237
- Publication Date:
- 2018-11-02
- Subjects:
- Iron -- Catalysis -- Density Functional Theory
Chemistry, Inorganic -- Periodicals
546 - Journal URLs:
- http://www.tandfonline.com/toc/gcic20/current ↗
http://www.tandfonline.com/ ↗ - DOI:
- 10.1080/02603594.2018.1539392 ↗
- Languages:
- English
- ISSNs:
- 0260-3594
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3336.028500
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 9468.xml