A facile approach for the synthesis of nido-carborane fused oxazoles via one pot deboronation/cyclization of 9-amide-o-carboranes. Issue 6 (21st December 2018)
- Record Type:
- Journal Article
- Title:
- A facile approach for the synthesis of nido-carborane fused oxazoles via one pot deboronation/cyclization of 9-amide-o-carboranes. Issue 6 (21st December 2018)
- Main Title:
- A facile approach for the synthesis of nido-carborane fused oxazoles via one pot deboronation/cyclization of 9-amide-o-carboranes
- Authors:
- Zhang, Cai-Yan
Cao, Ke
Xu, Tao-Tao
Wu, Ji
Jiang, Linhai
Yang, Junxiao - Abstract:
- Abstract : One pot deboronation/cyclization of 9-amide- o -carboranes for construction of nido -7, 8-carborane fused oxazoles. Abstract : A one pot deboronation/cyclization of 9-amide- o -carboranes for the synthesis of nido -7, 8-carborane fused oxazole by cooperation of Pd(OAc)2, AgOAc and K2 CO3 has been developed. A plausible mechanism involving an amide directed electrophilic palladation of the B–H bond and deboronation/cyclization process was proposed based on the successful isolation and structural characterization of the key deboronated intermediate.
- Is Part Of:
- Chemical communications. Volume 55:Issue 6(2019)
- Journal:
- Chemical communications
- Issue:
- Volume 55:Issue 6(2019)
- Issue Display:
- Volume 55, Issue 6 (2019)
- Year:
- 2019
- Volume:
- 55
- Issue:
- 6
- Issue Sort Value:
- 2019-0055-0006-0000
- Page Start:
- 830
- Page End:
- 833
- Publication Date:
- 2018-12-21
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c8cc07728b ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 9469.xml