Difluorocarbene-derived trifluoromethylselenolation of benzyl halides. Issue 10 (14th January 2019)
- Record Type:
- Journal Article
- Title:
- Difluorocarbene-derived trifluoromethylselenolation of benzyl halides. Issue 10 (14th January 2019)
- Main Title:
- Difluorocarbene-derived trifluoromethylselenolation of benzyl halides
- Authors:
- Chen, Xin-Lei
Zhou, Sheng-Hua
Lin, Jin-Hong
Deng, Qing-Hai
Xiao, Ji-Chang - Abstract:
- Abstract : Cu-Promoted difluorocarbene-derived trifluoromethylselenolation of benzyl halides with the Ph3 P + CF2 CO2 − /Se /F − system is described. Abstract : Cu-Promoted difluorocarbene-derived trifluoromethylselenolation of benzyl halides with the Ph3 P + CF2 CO2 − /Se /F − system is described. Three new carbon–heteroatom bonds, a Se–CF2 bond, SeCF2 –F bond, and C–SeCF3 bond, were sequentially formed in the reaction. This work represents the first trifluoromethylselenolation protocol involving an external fluoride for the generation of the key intermediate, CF3 Se − anion.
- Is Part Of:
- Chemical communications. Volume 55:Issue 10(2019)
- Journal:
- Chemical communications
- Issue:
- Volume 55:Issue 10(2019)
- Issue Display:
- Volume 55, Issue 10 (2019)
- Year:
- 2019
- Volume:
- 55
- Issue:
- 10
- Issue Sort Value:
- 2019-0055-0010-0000
- Page Start:
- 1410
- Page End:
- 1413
- Publication Date:
- 2019-01-14
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c8cc09719d ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 9473.xml