Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(i) oxide. Issue 6 (14th January 2019)

• Record Type: Journal Article
• Authors: Marr, Andrew C.; Morgan, Patrick J.; Saunders, Graham C.; Thomas, Hayden P.
• Is Part Of: Dalton transactions. Volume 48:Issue 6(2019)
• Page Start: 1947
• Page End: 1949
• Publication Date: 2019-01-14
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c8dt04456b
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : The reaction between haloform, the complexes [Cp*IrCl2 (κC-MeNC3 H2 NCH2 Ar)] (Ar = C6 H3 F2 -2, 6, C6 H3 F-2-Cl-6, C6 H3 Me2 -2, 6) and silver(i ) oxide proceeded by carbon–halogen bond fission to yield the carbonate complexes [Cp*Ir(κ 2 O-CO3 )(κC-MeNC3 H2 NCH2 Ar)]. Abstract : The reaction between haloform, the complexes [Cp*IrCl2 (κC-MeNC3 H2 NCH2 Ar)] (Ar = C6 H3 F2 -2, 6, C6 H3 F-2-Cl-6, C6 H3 Me2 -2, 6) and silver(i ) oxide proceeded by carbon–halogen bond fission to yield the carbonate complexes [Cp*Ir(κ 2 O-CO3 )(κC-MeNC3 H2 NCH2 Ar)].