Rare metal-ion metathesis of a tetrahedral Zn(ii) core of a noncentrosymmetric (3, 4)-connected 3D MOF. Issue 6 (15th January 2019)

• Record Type: Journal Article
• Authors: Lee, Li-Wei; Kao, Ya-Chuan; Chung, Mei-Ying; Chang, Bor-Chen; Lee, Gene-Hsiang; Peng, Shie-Ming; Wang, Chih-Min; Liu, Yen-Hsiang; Lee, Sheng-Long; Lu, Kuang-Lieh
• Is Part Of: Dalton transactions. Volume 48:Issue 6(2019)
• Page Start: 1950
• Page End: 1954
• Publication Date: 2019-01-15
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c8dt04472d
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : An SHG-active framework of1-Zn can undergo metal metathesis, in which the tetrahedrally coordinated Zn(ii ) ions are completely exchanged with Cu(ii ) ions while retaining the integrity of the network. Abstract : An SHG-active noncentrosymmetric (3, 4)-connected Zn(ii )–organic framework, {[Zn2 (4-abpt)(3, 4-pydc)2 ]·2DMAc·3MeOH·H2 O} n (1-Zn ), was synthesized using a mixed-ligand system. The1-Zn framework undergoes metal metathesis, with the complete exchange of the tetrahedrally coordinated Zn II ions with Cu II ions while retaining the integrity of the network.