Germylene–sulfoxide as a potential hemilabile ligand: application in coordination chemistry12. Issue 44 (22nd October 2018)

• Record Type: Journal Article
• Authors: Lentz, Nicolas; Mallet-Ladeira, Sonia; Baceiredo, Antoine; Kato, Tsuyoshi; Madec, David
• Is Part Of: Dalton transactions. Volume 47:Issue 44(2018)
• Page Start: 15751
• Page End: 15756
• Publication Date: 2018-10-22
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c8dt03669a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Heteroleptic organogermylenes containing a sulfoxide donor function were used for application in coordination chemistry with [W(cod)(CO)4 ], [Mo(nbd)(CO)4 ] and [Ru(PPh3 )3 Cl2 ]. Abstract : We describe here the synthesis of heteroleptic organogermylenes containing a sulfoxide donor function for their application in coordination chemistry. While complexation reaction with [W(cod)(CO)4 ] and [Mo(nbd)(CO)4 ] afforded bis(germanium)(ii ) transition-metal complexes, a bidentate complex coordinated by germanium(ii ) and the oxygen atom of the sulfinyl group was obtained from [Ru(PPh3 )3 Cl2 ].