Photo-oxidative degradation of methylammonium lead iodide perovskite: mechanism and protection. Issue 5 (14th January 2019)

• Record Type: Journal Article
• Authors: Ouyang, Yixin; Li, Yajuan; Zhu, Pengchen; Li, Qiang; Gao, Yuan; Tong, Jianyu; Shi, Li; Zhou, Qionghua; Ling, Chongyi; Chen, Qian; Deng, Zhengtao; Tan, Hairen; Deng, Weiqiao; Wang, Jinlan
• Is Part Of: Journal of materials chemistry. Volume 7:Issue 5(2019)
• Page Start: 2275
• Page End: 2282
• Publication Date: 2019-01-14
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c8ta12193a
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : A new three-step photo-oxidative degradation mechanism of MAPbI3 is proposed. A strategy for protecting MAPbI3 by 2-(4-fluorophenyl)propan-2-amine modification is designed. Abstract : Although the power conversion efficiency of perovskite solar cells has exceeded 23%, the poor ambient stability of organic–inorganic halide perovskites poses a challenge for their commercialization. Comprehensive understanding of the underlying degradation mechanisms is a crucial step to seek approaches that can effectively suppress the degradation of perovskites. Herein, on the basis of extensive first-principles calculations, a three-step photo-oxidative degradation mechanism of MAPbI3 at the atomic level is revealed. We find that, in a dry ambient environment, the photo-generated superoxide anions (O2 − ) first lead to fast surface oxidation. However, further oxidation of the perovskite interior is hindered by the solid oxidation product. The fresh water produced in surface oxidation leads to the hydration of the inner perovskite and eventual breakage of the MAPbI3 lattice. We devise a practical strategy for protecting MAPbI3 from photo-induced decomposition by anchoring hydrophobic 2-(4-fluorophenyl)propan-2-amine on the surface of MAPbI3 . The surface modification significantly retards the photo-induced decomposition.