PdCu/C anode catalysts for the alkaline ascorbate fuel cell. (1st February 2019)

• Record Type: Journal Article
• Authors: Muneeb, Omar; Do, Emily; Boyd, Desiree; Perez, Josh; Haan, John L.
• Is Part Of: Applied energy. Volume 235(2019)
• Page Start: 473
• Page End: 479
• Publication Date: 2019-02-01
• Subjects: Ascorbic acid -- Direct liquid fuel cell -- Copper -- Palladium -- Electronic effect -- Bifunctional effect; Power (Mechanics) -- Periodicals; Energy conservation -- Periodicals; Energy conversion -- Periodicals; 621.042
• DOI: 10.1016/j.apenergy.2018.10.073
• Languages: English
• ISSNs: 0306-2619

Abstract

Graphical abstract: Highlights: Pd28 Cu72 /C increases (per surface area) the maximum power density of the ascorbate fuel cell by 68%. Pd28 Cu72 /C increases (per mass Pd) the maximum power density of the ascorbate fuel cell by a factor of 6. Pd11 Cu89 /C increases current density for ascorbate oxidation by a factor of 6.8 in a half cell. Increased efficiency when Cu added to Pd catalyst is from electronic and bifunctional effects. Abstract: In this work, PdCu/C catalysts are used to increase the power output of an alkaline ascorbate fuel cell using an alkaline anion exchange membrane. The alkaline ascorbate fuel cell produces significantly more power than a direct ascorbic acid fuel cell using an acidic cation exchange membrane. However, that alkaline ascorbate fuel cell employs Pd catalyst at the anode. Since addition of Cu to a Pd catalyst results in higher oxidation rates for polyalcohol oxidation in alkaline media, we add Cu to this Pd catalyst to study its impact on ascorbate oxidation in alkaline media. The ascorbate fuel cell maximum power density increases from 53 mW cm −2 when Pd/C is used at the anode to 89 mW cm −2 when Pd28 Cu72 /C is used. Per mass of Pd, the Pd/C anode produces only 32 mW mg −1 while the Pd28 Cu72 /C anode produces 194 mW mg −1 . Electrochemical analysis of various PdCu/C catalysts shows that the current density after oxidation at −0.4 V for 1 h increases with the addition of greater quantities of Cu to the Pd catalyst, from 0.111 mA cm −2 on Pd/C to 0.757 mA cm −2 on Pd11 Cu89 /C. This increase in catalytic efficiency when Cu is added to the Pd catalyst is attributed to a combination of the electronic and bifunctional effects.