Asymmetric selenophene-based non-fullerene acceptors for high-performance organic solar cells. Issue 4 (10th January 2019)

• Record Type: Journal Article
• Authors: Li, Chao; Xia, Tian; Song, Jiali; Fu, Huiting; Ryu, Hwa Sook; Weng, Kangkang; Ye, Linglong; Woo, Han Young; Sun, Yanming
• Is Part Of: Journal of materials chemistry. Volume 7:Issue 4(2019)
• Page Start: 1435
• Page End: 1441
• Publication Date: 2019-01-10
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c8ta11197a
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : Two novel selenophene-containing building blocks have been developed as central cores to construct high-performance asymmetric non-fullerene acceptors (SePTT-2F and SePTTT-2F). Organic solar cells based on SePTTT-2F with more extended backbone conjugation delivered a high efficiency of 12.24% with an outstanding fill factor of 75.9%. Abstract : Compared to thiophene-based non-fullerene acceptors (NFAs), selenophene-based NFAs have received much less attention. And organic solar cells (OSCs) based on selenophene-containing NFAs typically exhibit relatively low power conversion efficiency (PCE < 12%) and fill factor (FF < 70%). In this contribution, we have designed and synthesized two asymmetric selenophene-based NFAs, named SePTT-2F and SePTTT-2F, which possess the same end-capping group but different selenophene-containing conjugated backbones. On comparing the two NFAs, SePTTT-2F with more extended conjugation in the backbone was found to have almost the same maximum absorption peak and optical bandgap in film as SePTT-2F but an up-shifted lowest unoccupied molecular orbital (LUMO) energy level and higher electron mobility. By pairing the NFAs with the polymer donor PBT1-C, the resultant blend film based on SePTTT-2F exhibited higher and more balanced charge mobilities and more efficient exciton dissociation and charge collection in comparison with the SePTT-2F-based blend film. As a result, OSCs based on SePTTT-2F delivered an impressively high PCE of 12.24% with an outstanding FF of 75.9%, much higher than those of the SePTT-2F-based OSCs. To the best of our knowledge, the PCE of 12.24% and FF of 75.9% are among the highest values reported in the literature so far for both the parameters amongst selenophene-containing NFA-based OSCs. Our results demonstrate that extending the conjugation in the selenophene-containing backbone is an effective strategy to design highly efficient selenophene-based NFAs.