Quantitative analysis of sub-ppm traces of hydrocarbons in the product gas from diesel reforming. (8th February 2019)

• Record Type: Journal Article
• Authors: Meißner, J.; Pasel, J.; Peters, R.; Samsun, R.C.; Thimm, F.; Stolten, D.
• Is Part Of: International journal of hydrogen energy. Volume 44:Number 8(2019)
• Page Start: 4020
• Page End: 4030
• Publication Date: 2019-02-08
• Subjects: Autothermal reforming -- Diesel -- Contaminants -- Impurities -- PEM fuel cell -- Auxiliary power unit; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2018.12.175
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: The autothermal reforming of middle distillates is a favored reforming technique for fuel cell-based auxiliary power units (APUs) in the transport sector. The efforts made in recent years to produce a high quality reformate have been reflected in a variety of improvements to the reactors and mode of operation of the fuel processing systems. By these means, the concentrations of contaminants, especially traces of hydrocarbons in the gas phase, frequently drops below the previous detection limit. In this paper, a new GC/MS method is developed to reduce the detection limit of the analytics into the sub-ppm range. This work is intended to serve as a valuable step to showing which traces of hydrocarbons can still be qualitatively and quantitatively expected in a high quality reformate. This contribution may help determine the multitude of hydrocarbonous substances that can have a detrimental long-term effect on catalysts and adsorbents in a fuel cell-based APU system operated with middle distillates. Highlights: GC/MS method was optimized to find hydrocarbon trace in sub-ppm range. Multitude of contaminants in a high quality diesel reformate where identified. 12 Representative contaminants up to C7 were quantitatively determined.