Toughening of silicon nitride ceramics by addition of multilayer graphene. Issue 4 (March 2019)

• Record Type: Journal Article
• Authors: Bódis, Eszter; Cora, Ildikó; Németh, Péter; Tapasztó, Orsolya; Mohai, Miklós; Tóth, Sára; Károly, Zoltán; Szépvölgyi, János
• Is Part Of: Ceramics international. Volume 45:Issue 4(2019)
• Page Start: 4810
• Page End: 4816
• Publication Date: 2019-03
• Subjects: Ceramics -- Periodicals; Céramique industrielle -- Périodiques; Ceramics; Periodicals; Electronic journals; 666
• DOI: 10.1016/j.ceramint.2018.11.176
• Languages: English
• ISSNs: 0272-8842

Abstract

Abstract: Silicon nitride (Si3 N4 ) ceramics have superior mechanical properties allowing their broad application in many technical fields. In this work, Si3 N4 -based composites with 1–5 wt% multilayer graphene (MLG) content were fabricated by spark plasma sintering at different temperatures and holding time in order to improve the fracture resistance of the Si3 N4 ceramic. Our investigation focused on understanding the relationships between the microstructure and mechanical properties with special attention to the intergranular phases between Si3 N4 matrix and MLG reinforcement. We have found that nanopores developed at the Si3 N4 -MLG interface due to a reaction between carbon and the oxygen available in the topmost layer of the Si3 N4 particles. Interface porosity has an optimum for the toughening effect. In 1 wt% MLG/Si3 N4 composites nanopores are local, but separated at the Si3 N4 -MLG interface, which promote the MLG pull-out mechanism imparting a significant toughening effect on the composite. Beyond the optimal 1 wt% MLG content, MLG platelets agglomerate and excessive porosity are developed at the Si3 N4 -MLG interfaces, leading to weaker matrix- graphene adhesion and thus lower fracture toughness.