Enhanced efficiency in perovskite solar cells by eliminating the electron contact barrier between the metal electrode and electron transport layer. Issue 3 (2nd January 2019)

• Record Type: Journal Article
• Authors: Tao, Junlei; Ali, Nasir; Chen, Kang; Huai, Zhaoxiang; Sun, Yansheng; Fu, Guangsheng; Kong, Weiguang; Yang, Shaopeng
• Is Part Of: Journal of materials chemistry. Volume 7:Issue 3(2019)
• Page Start: 1349
• Page End: 1355
• Publication Date: 2019-01-02
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c8ta10630d
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : Interface modifying layers (IMLs) play a pivotal role in the improved performance of perovskite solar cells (PSCs). Abstract : Interface modifying layers (IMLs) play a pivotal role in the improved performance of perovskite solar cells (PSCs). Herein, we report a new IML based on Bphen:Cs2 CO3 :BCP (BCB), which is inserted at the interface of phenyl-C61 -butyric acid methyl ester (PC61 BM) and a Ag electrode. Consequently, the efficiency of PSCs is significantly improved by 5% (from 17.57% to 18.29%), mainly due to the increased open circuit voltage ( V OC ). It is revealed by ultraviolet photoelectron spectroscopy (UPS) that the work function of Ag is reduced from 4.68 eV to 3.90 eV, after being modified by BCB due to the formation of a strong negative interfacial dipole at the Ag/BCB interface. The decreased work function of Ag improves the ohmic contact between PC61 BM and Ag, facilitating carrier extraction and suppressing the charge recombination at the interface of PC61 BM and the Ag electrode. As a result, the reverse saturation current of the final PSC is decreased by approximately one order of magnitude, which is consistent with a larger V OC . Our work provides a comprehensive understanding of the interface between a metal electrode and an electron transporting layer (ETL), and hence paves a way towards better interfacial engineering and highly efficient solar cells.