A photocatalytic sp3 C–S, C–Se and C–B bond formation through C–C bond cleavage of cycloketone oxime esters. Issue 3 (20th December 2018)

• Record Type: Journal Article
• Authors: Anand, Devireddy; He, Yuwei; Li, Linyong; Zhou, Lei
• Is Part Of: Organic & biomolecular chemistry. Volume 17:Issue 3(2018)
• Page Start: 533
• Page End: 540
• Publication Date: 2018-12-20
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c8ob02987c
• Languages: English
• ISSNs: 1477-0520

Abstract

Abstract : The photocatalytic sulfuration, selenylation and borylation of cycloketone oxime esters through iminyl radical-triggered C–C bond cleavage were described. The reactions provide a unified approach to alkyl sulfur, selenium and boron compounds tethered to a synthetically useful nitrile group. Abstract : The photocatalytic thiolation, selenylation and borylation of cycloketone oxime esters through iminyl radical-triggered C–C bond cleavage were described. The reactions provide a unified approach to alkyl sulfur, selenium and boron compounds tethered to a synthetically useful nitrile group.