Enhanced electroactivity and substrate affinity of microperoxidase-11 attached to pyrene-linkers π–π stacked on carbon nanostructure electrodes. Issue 16 (21st January 2015)

• Record Type: Journal Article
• Authors: Prasad, K. Sudhakara; Walgama, Charuksha; Krishnan, Sadagopan
• Is Part Of: RSC advances. Volume 5:Issue 16(2015)
• Page Start: 11845
• Page End: 11849
• Publication Date: 2015-01-21
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c4ra14361b
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : An exceptionally large electroactively connected microperoxidase-11 (MP-11) with strong affinity for organic peroxide and offering a high electrocatalytic reduction current density of 7.5 mA cm −2 is achieved for the first time. Abstract : An exceptionally large electroactively connected microperoxidase-11 (MP-11) with strong affinity for organic peroxide and offering a high electrocatalytic reduction current density of 7.5 mA cm −2 is achieved for the first time. For this, MP-11 was attached via pyrene linkers on the surface of multiwalled carbon nanotube-modified graphite electrodes.