Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study. Issue 8 (22nd January 2018)

• Record Type: Journal Article
• Authors: Agonigi, Gabriele; Bortoluzzi, Marco; Marchetti, Fabio; Pampaloni, Guido; Zacchini, Stefano; Zanotti, Valerio
• Is Part Of: European journal of inorganic chemistry. Issue 8(2018)
• Page Start: 959
• Page End: 959
• Publication Date: 2018-01-22
• Subjects: Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.201800063
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract: Invited for the cover of this issue is the group of Fabio Marchetti from the University of Pisa, Italy. The cover image shows the X‐ray structure of a cationic diiron carbonyl cyclopentadienide complex with a bridging aminocarbyne ligand and the sites suitable for regioselective addition of nucleophiles. Abstract : Basic research in synthetic organometallic chemistry is a fantastic journey through the discovery of novel pathways, mechanisms and structures, and the perspectives of this exploration are often unpredictable and somehow unlimited… Read more about the story behind the cover in the Cover Profile and about the research itself in theFull Paper by F. Marchetti et al.