Vinylidenation of Organoboronic Esters Enabled by a Pd‐Catalyzed Metallate Shift. (12th December 2018)
- Record Type:
- Journal Article
- Title:
- Vinylidenation of Organoboronic Esters Enabled by a Pd‐Catalyzed Metallate Shift. (12th December 2018)
- Main Title:
- Vinylidenation of Organoboronic Esters Enabled by a Pd‐Catalyzed Metallate Shift
- Authors:
- Aparece, Mark D.
Gao, Chenpeng
Lovinger, Gabriel J.
Morken, James P. - Abstract:
- Abstract: Organoboron "ate" complexes undergo a net vinyl insertion reaction to give 1, 1‐disubstituted alkenyl boronic esters when treated with stoichiometric allyl acetate and a palladium catalyst. Reactions that employ vinyllithium afforded good to excellent yields after one hour, while reactions that employ vinylmagnesium chloride furnished modest to good yields after 18 hours.
- Is Part Of:
- Angewandte Chemie. Volume 131:Number 2(2019)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 131:Number 2(2019)
- Issue Display:
- Volume 131, Issue 2 (2019)
- Year:
- 2019
- Volume:
- 131
- Issue:
- 2
- Issue Sort Value:
- 2019-0131-0002-0000
- Page Start:
- 602
- Page End:
- 605
- Publication Date:
- 2018-12-12
- Subjects:
- Allylkomplexe -- Bor -- Homogene Katalyse -- Palladium
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201811782 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 9379.xml