Manganese‐Catalyzed Carbonylative Annulations for Redox‐Neutral Late‐Stage Diversification. (6th April 2018)
- Record Type:
- Journal Article
- Title:
- Manganese‐Catalyzed Carbonylative Annulations for Redox‐Neutral Late‐Stage Diversification. (6th April 2018)
- Main Title:
- Manganese‐Catalyzed Carbonylative Annulations for Redox‐Neutral Late‐Stage Diversification
- Authors:
- Liang, Yu‐Feng
Steinbock, Ralf
Münch, Annika
Stalke, Dietmar
Ackermann, Lutz - Abstract:
- Abstract: An inexpensive, nontoxic manganese catalyst enabled unprecedented redox‐neutral carbonylative annulations under ambient pressure. The manganese catalyst outperformed all other typically used base and precious‐metal catalysts. The outstanding versatility of the manganese catalysis manifold was reflected by ample substrate scope, setting the stage for effective late‐stage manipulations under racemization‐free conditions of a wealth of marketed drugs and natural products, including alkaloids, amino acids, steroids, and carbohydrates.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 19(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 19(2018)
- Issue Display:
- Volume 130, Issue 19 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 19
- Issue Sort Value:
- 2018-0130-0019-0000
- Page Start:
- 5482
- Page End:
- 5486
- Publication Date:
- 2018-04-06
- Subjects:
- Anellierungen -- Carbonylierungen -- Mangan -- Späte Modifizierungen -- Spurlose dirigierende Gruppen
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201801111 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 9343.xml