Nanomechanics of Poly(catecholamine) Coatings in Aqueous Solutions. Issue 10 (2nd February 2016)

• Record Type: Journal Article
• Authors: Lim, Chanoong; Huang, Jun; Kim, Sunjin; Lee, Haeshin; Zeng, Hongbo; Hwang, Dong Soo
• Is Part Of: Angewandte Chemie international edition. Volume 55:Issue 10(2016)
• Page Start: 3342
• Page End: 3346
• Publication Date: 2016-02-02
• Subjects: adhesive strength -- catecholamine -- cation–π interaction -- coatings -- π interactions; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201510319
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract: Mussel‐inspired self‐polymerized catecholamine coatings have been widely utilized as a versatile coating strategy that can be applied to a variety of substrates. For the first time, nanomechanical measurements and an evaluation of the contribution of primary amine groups to poly(catecholamine) coatings have been conducted using a surface‐forces apparatus. The adhesive strength between the poly(catecholamine) layers is 30‐times higher than that of a poly(catechol) coating. The origin of the strong attraction between the poly(catecholamine) layers is probably due to surface salt displacement by the primary amine, π–π stacking (the quadrupole–quadrupole interaction of indolic crosslinks), and cation–π interactions (the monopole–quadrupole interaction between positively charged amine groups and the indolic crosslinks). The contribution of the primary amine group to the catecholamine coating is vital for the design and development of mussel‐inspired catechol‐based coating materials. Abstract : Give it some stick : The adhesive strength of self‐polymerized catecholic coating layers was measured with a surface forces apparatus. The adhesive strength between poly(catecholamine) layers is 30‐times higher than that between poly(catechol) layers. The origin of the strong attraction between poly(catecholamine) layers is possibly due to surface salt displacement, π–π stacking, and cation–π interactions involving the primary amine moiety.