Rhodium‐Catalyzed Cross‐Cyclotrimerization and Dimerization of Allenes with Alkynes. (25th April 2016)
- Record Type:
- Journal Article
- Title:
- Rhodium‐Catalyzed Cross‐Cyclotrimerization and Dimerization of Allenes with Alkynes. (25th April 2016)
- Main Title:
- Rhodium‐Catalyzed Cross‐Cyclotrimerization and Dimerization of Allenes with Alkynes
- Authors:
- Sakashita, Kazuki
Shibata, Yu
Tanaka, Ken - Abstract:
- Abstract: It has been established that a cationic rhodium(I)/binap complex catalyzes the cross‐cyclotrimerization of two molecules of a monosubstituted allene with one molecule of a functionalized alkyne to give 3, 6‐dialkylidenecyclohex‐1‐enes. In contrast, the reactions involving di‐ or trisubstituted allenes and/or unfunctionalized alkynes afforded cross‐dimerization products, substituted dendralenes, through β‐hydrogen elimination from the corresponding rhodacycles.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 23(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 23(2016)
- Issue Display:
- Volume 128, Issue 23 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 23
- Issue Sort Value:
- 2016-0128-0023-0000
- Page Start:
- 6865
- Page End:
- 6869
- Publication Date:
- 2016-04-25
- Subjects:
- Alkine -- Allene -- Cyclisierungen -- Dimerisierungen -- Rhodium
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201602155 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 9331.xml