Functional Organosulfide Electrolyte Promotes an Alternate Reaction Pathway to Achieve High Performance in Lithium–Sulfur Batteries. (25th February 2016)

• Record Type: Journal Article
• Authors: Chen, Shuru; Dai, Fang; Gordin, Mikhail L.; Yu, Zhaoxin; Gao, Yue; Song, Jiangxuan; Wang, Donghai
• Is Part Of: Angewandte Chemie. Volume 128:Number 13(2016)
• Page Start: 4303
• Page End: 4307
• Publication Date: 2016-02-25
• Subjects: Batterien -- Dimethyldisulfid -- Elektrolyte -- Lithium-Schwefel-Batterien -- Organische Sulfide; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201511830
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Lithium–sulfur (Li‐S) batteries have recently received great attention because they promise to provide energy density far beyond current lithium ion batteries. Typically, Li‐S batteries operate by conversion of sulfur to reversibly form different soluble lithium polysulfide intermediates and insoluble lithium sulfides through multistep redox reactions. Herein, we report a functional electrolyte system incorporating dimethyl disulfide as a co‐solvent that enables a new electrochemical reduction pathway for sulfur cathodes. This pathway uses soluble dimethyl polysulfides and lithium organosulfides as intermediates and products, which can boost cell capacity and lead to improved discharge–charge reversibility and cycling performance of sulfur cathodes. This electrolyte system can potentially enable Li‐S batteries to achieve high energy density.