Direct N‐Glycofunctionalization of Amides with Glycosyl Trichloroacetimidate by Thiourea/Halogen Bond Donor Co‐Catalysis. (5th March 2018)
- Record Type:
- Journal Article
- Title:
- Direct N‐Glycofunctionalization of Amides with Glycosyl Trichloroacetimidate by Thiourea/Halogen Bond Donor Co‐Catalysis. (5th March 2018)
- Main Title:
- Direct N‐Glycofunctionalization of Amides with Glycosyl Trichloroacetimidate by Thiourea/Halogen Bond Donor Co‐Catalysis
- Authors:
- Kobayashi, Yusuke
Nakatsuji, Yuya
Li, Shanji
Tsuzuki, Seiji
Takemoto, Yoshiji - Abstract:
- Abstract: Using a halogen bond (XB) donor and Schreiner's thiourea as cooperative catalysts, various amides, including the asparagine residues of several peptides, were directly coupled with glycosyl trichloroacetimidates to give unique N‐acylorthoamides in good yields. Synthetic applications of N‐acylorthoamides, including rearrangement to the corresponding β‐N‐glycoside, were also demonstrated.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 14(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 14(2018)
- Issue Display:
- Volume 130, Issue 14 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 14
- Issue Sort Value:
- 2018-0130-0014-0000
- Page Start:
- 3708
- Page End:
- 3712
- Publication Date:
- 2018-03-05
- Subjects:
- Brønsted-Säure-Katalyse -- Glycosylierung -- Kohlenhydrate -- Organokatalyse
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201712726 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 9318.xml