Base–Metal‐Catalyzed Regiodivergent Alkene Hydrosilylations. (25th April 2016)
- Record Type:
- Journal Article
- Title:
- Base–Metal‐Catalyzed Regiodivergent Alkene Hydrosilylations. (25th April 2016)
- Main Title:
- Base–Metal‐Catalyzed Regiodivergent Alkene Hydrosilylations
- Authors:
- Du, Xiaoyong
Zhang, Yanlu
Peng, Dongjie
Huang, Zheng - Abstract:
- Abstract: A complementary set of base metal catalysts has been developed for regiodivergent alkene hydrosilylations: iron complexes of phosphine‐iminopyridine are selective for anti ‐Markovnikov hydrosilylations (linear/branched up to >99:1), while the cobalt complexes bearing the same type of ligands provide an unprecedented high level of Markovnikov selectivity (branched/linear up to >99:1). Both systems exhibit high efficiency and wide functional group tolerance.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 23(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 23(2016)
- Issue Display:
- Volume 128, Issue 23 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 23
- Issue Sort Value:
- 2016-0128-0023-0000
- Page Start:
- 6783
- Page End:
- 6787
- Publication Date:
- 2016-04-25
- Subjects:
- Alkene -- Cobalt -- Eisen -- Homogene Katalyse -- Hydrosilylierung
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201601197 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 9317.xml