Self‐Propelled Rolled‐Up Polyelectrolyte Multilayer Microrockets. (15th January 2018)

• Record Type: Journal Article
• Authors: Hu, Narisu; Sun, Mengmeng; Lin, Xiankun; Gao, Changyong; Zhang, Bin; Zheng, Ce; Xie, Hui; He, Qiang
• Is Part Of: Advanced functional materials. Volume 28:Number 25(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-01-15
• Subjects: cell manipulation -- layer‐by‐layer assembly -- micromotor -- rolled‐up technology -- self‐propulsion; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.201705684
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: Engineering self‐propelled micro‐/nanomachines with ultrafast speeds and high towing forces is crucial for the efficient transportation of important objects in key biomedical and environmental applications. In this study, rolled‐up nanomembrane technology is used for the first time for the controlled fabrication of layer‐by‐layer (LbL)‐assembled microtubes and the corresponding chemical‐powered microrockets. By integrating LbL assembly, microcontact printing, and a rolled‐up nanomembrane technique, polyelectrolyte multilayer microplates of different shapes are transformed into well‐defined microtubes. Coupled with platinum nanoparticles, the as‐prepared microtubes can act as bubble‐propelled microrockets with a very rapid speed and a large towing force. As a proof of concept, the rolled LbL microrockets confirm the feasibility of transporting single or multiple cells at high speed. Integrating the rolled‐up nanomembrane technology and LbL assembly results in a simple, versatile, and low‐cost approach and expands the scope of both polymer multilayer‐based multifunctional tubes and artificial machines at the micro‐/nanoscale. Abstract : Self‐propelled rolled‐up microrockets based on layer‐by‐layer (LbL) assembly are presented. The self‐rolling of polyelectrolyte multilayer microplates, prepared by combining LbL assembly and microcontact printing, produces rolled‐up microtubes. Through integrating platinum nanoparticles, the microtubes are transformed into bubble‐propelled microrockets. The curling structure of the microrockets yields superfast speeds and large towing forces for transporting single or multiple cells.