Fe2P4O12–carbon composite as a highly stable electrode material for electrochemical capacitors. (30th November 2018)

• Record Type: Journal Article
• Authors: Soni, Roby; Kurungot, Sreekumar
• Is Part Of: New journal of chemistry. Volume 43:Number 1(2019)
• Page Start: 399
• Page End: 406
• Publication Date: 2018-11-30
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/c8nj04671a
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : A carbon–iron cyclotetraphosphate composite derived from the pyrolysis of a ferric phytate gel is demonstrated as a high-performance and highly durable capacitive material. Abstract : Supercapacitors are important energy storage devices for high power applications. Carbon materials, metal oxides and conducting polymers have been known to show capacitive charge storage but transition metal phosphates are not as well-known as electrode materials in supercapacitors. In this study, an iron cyclotetraphosphate (Fe2 P4 O12 )–carbon composite has been synthesized and demonstrated as an electrode material for supercapacitors. The Fe2 P4 O12 –carbon composite has been thoroughly characterized by X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction, electron microscopy, etc. The composite shows predominant capacitive behaviour only in acidic medium; its charge storage properties are relatively poor in alkaline medium, indicating the important role of H + in the charge storage mechanism. The composite shows a capacitance of 251 F g −1 at a current density of 1 A g −1 . The composite is highly stable in 0.5 M H2 SO4 and does not show any apparent capacitance loss after 9000 charge–discharge cycles recorded at a current density of 5 A g −1 .