Reversible redox inter-conversion of biologically active NAD+/NADH derivatives bound to a gold electrode: ToF-SIMS evidence. Issue 99 (20th November 2018)

• Record Type: Journal Article
• Authors: Qian, Ruo-Can; Zhao, Li-Jun; Lv, Jian; Hua, Xin; Long, Yi-Tao
• Is Part Of: Chemical communications. Volume 54:Issue 99(2018)
• Page Start: 13945
• Page End: 13948
• Publication Date: 2018-11-20
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c8cc08341j
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The electrochemical reversible redox of NAD + /NADH is realized, which is confirmed by time-of-flight secondary ion mass spectrometry. Abstract : The realization of the reversible inter-conversion between NADH and NAD + is a long-term challenge in biological and energy-related chemistry. Here, we achieve the electrochemical reversible redox of NAD + /NADH derivatives by the functionalization of a gold electrode with a specially designed NAD + derivative, and the electrochemical redox products are characterized by time-of-flight secondary ion mass spectrometry (ToF-SIMS).