Divergent surface properties of multidimensional sp2 carbon allotropes: the effect of aging phenomena. (10th June 2016)

• Record Type: Journal Article
• Authors: Chang, Yun-Hsiang; Olukan, Tuza; Lai, Chia-Yun; Marbou, Khalid; Apostoleris, Harry N; Ghaferi, Amal Al; Chiesa, Matteo
• Is Part Of: Nanotechnology. Volume 27:Number 29(2016)
• Publication Date: 2016-06-10
• Subjects: surface property -- sp2 carbon allotropes -- aging phenomena -- atomic force microscopy; Nanotechnology -- Periodicals; Nanotechnology -- Periodicals; Nanotechnology; Publications périodiques; Nanotechnologies; Periodicals; 620.5
• DOI: 10.1088/0957-4484/27/29/295701
• Languages: English
• ISSNs: 0957-4484

Abstract

Abstract: Despite the current interest in the scientific community in exploiting divergent surface properties of graphitic carbon allotropes, conclusive differentiation remains elusive even when dealing with parameters as fundamental as adhesion. Here, we set out to provide conclusive experimental evidence on the time evolution of the surface properties of highly oriented pyrolytic graphite (HOPG), graphene monolayer (GML) and multiwalled carbon nanotubes (MWCNTs) as we expose these materials to airborne contaminants, by providing (1) statistically significant results based on large datasets consisting of thousands of force measurements, and (2) errors sufficiently self-consistent to treat the comparison between datasets in atomic force microscopy (AFM) measurements. We first consider HOPG as a model system and then employ our results to draw conclusions from the GML and MWCNT samples. We find that the surface properties of aged HOPG are indistinguishable from those of aged GML and MWCNT, while being distinct from those of cleaved HOPG. Herein, we provide a sufficient body of evidence to disregard any divergence in surface properties for multidimensional sp 2 carbon allotropes that undergo similar aging processes.