A Manganese Pre‐Catalyst: Mild Reduction of Amides, Ketones, Aldehydes, and Esters. (14th November 2017)
- Record Type:
- Journal Article
- Title:
- A Manganese Pre‐Catalyst: Mild Reduction of Amides, Ketones, Aldehydes, and Esters. (14th November 2017)
- Main Title:
- A Manganese Pre‐Catalyst: Mild Reduction of Amides, Ketones, Aldehydes, and Esters
- Authors:
- Kelly, Colin M.
McDonald, Robert
Sydora, Orson L.
Stradiotto, Mark
Turculet, Laura - Abstract:
- Abstract: A new ( N ‐phosphinoamidinate)manganese complex is shown to be a useful pre‐catalyst for the hydrosilative reduction of carbonyl compounds, and in most cases at room temperature. The Mn‐catalyzed reduction of tertiary amides to tertiary amines, with a useful scope, is demonstrated for the first time by use of this catalyst, and is competitive with the most effective transition‐metal catalysts known for such transformations. Ketones, aldehydes, and esters were also successfully reduced under mild conditions by using this new Mn catalyst.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 50(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 50(2017)
- Issue Display:
- Volume 129, Issue 50 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 50
- Issue Sort Value:
- 2017-0129-0050-0000
- Page Start:
- 16117
- Page End:
- 16120
- Publication Date:
- 2017-11-14
- Subjects:
- Amide -- Carbonylverbindungen -- Mangan -- Reduktionen -- Synthesemethoden
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201709441 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 9185.xml