Conversion of Olefins into Ketones by an Iron‐Catalyzed Wacker‐type Oxidation Using Oxygen as the Sole Oxidant1. (28th December 2017)
- Record Type:
- Journal Article
- Title:
- Conversion of Olefins into Ketones by an Iron‐Catalyzed Wacker‐type Oxidation Using Oxygen as the Sole Oxidant1. (28th December 2017)
- Main Title:
- Conversion of Olefins into Ketones by an Iron‐Catalyzed Wacker‐type Oxidation Using Oxygen as the Sole Oxidant1
- Authors:
- Puls, Florian
Knölker, Hans‐Joachim - Abstract:
- Abstract: We describe a mild and operationally simple procedure for the oxidation of olefins into ketones. The reaction is catalyzed by the hexadecafluorinated iron–phthalocyanine complex FePcF16 with stoichiometric amounts of triethylsilane as an additive under oxygen atmosphere to give ketones in good to high yields with excellent chemoselectivity and functional group tolerance. Ketone formation proceeds in up to 95 % yield and with 100 % regioselectivity while the corresponding alcohols were observed as side products.
- Is Part Of:
- Angewandte Chemie. Volume 130:Number 5(2018)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 130:Number 5(2018)
- Issue Display:
- Volume 130, Issue 5 (2018)
- Year:
- 2018
- Volume:
- 130
- Issue:
- 5
- Issue Sort Value:
- 2018-0130-0005-0000
- Page Start:
- 1236
- Page End:
- 1240
- Publication Date:
- 2017-12-28
- Subjects:
- Eisen -- Homogene Katalyse -- Ketone -- Olefine -- Phthalocyanine
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201710370 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 9174.xml