Decarboxylative Fluorination of Arylcarboxylic Acids Promoted by ortho‐Hydroxy and Amino Groups2. Issue 6 (17th April 2018)

• Record Type: Journal Article
• Authors: Wang, Dinghai; Yuan, Zheliang; Liu, Qilun; Chen, Pinhong; Liu, Guosheng
• Is Part Of: Chinese journal of chemistry. Volume 36:Issue 6(2018)
• Page Start: 507
• Page End: 514
• Publication Date: 2018-04-17
• Subjects: metal‐free -- decarboxylative -- fluorination -- aryl carboxylic acids; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/cjoc.201800016
• Languages: English
• ISSNs: 1001-604X

Abstract

Abstract: A novel decarboxylative fluorination process has been developed for the synthesis of ortho ‐hydroxy/amino arylfluorides from salicylic acid analogs, in which the ortho ‐hydroxy/amino group plays an important role in the transformation. In addition, various arylfluorides are obtained in good to excellent yields under mild conditions. Abstract : A novel decarboxylative fluorination process has been developed for the synthesis of ortho ‐ hydroxy/amino arylfluorides from salicylic acid analogs, in which the ortho ‐hydroxy/amino groups play an important role in the transformation. In addition, various arylfluorides are obtained in good to excellent yields under mild conditions.