Enolate Stabilization by Anion–π Interactions: Deuterium Exchange in Malonate Dilactones on π‐Acidic Surfaces. Issue 8 (19th January 2016)

• Record Type: Journal Article
• Authors: Miros, François N.; Zhao, Yingjie; Sargsyan, Gevorg; Pupier, Marion; Besnard, Céline; Beuchat, César; Mareda, Jiri; Sakai, Naomi; Matile, Stefan
• Is Part Of: Chemistry. Volume 22:Issue 8(2016)
• Page Start: 2545
• Page End: 2545
• Publication Date: 2016-01-19
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201504673
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: Invited for the cover of this issue is the group of Stefan Matile at the University of Geneva. The cover image depicts the crystal structure of a malonate dilactone placed on a chiral π‐acidic surface to measure enolate–π interactions during deuterium exchange. Read the full text of the article at10.1002/chem.201504008 . Abstract : " The hypothesis that enolates can be stabilized on aromatic surfaces is validated with highest possible certainty ." Read more about the story behind the cover in the Cover Profile and about the research itself on page 2648 ff. (DOI:10.1002/chem.201504008 ).