Solution Processed Coating of Polyolefin on Melamine Foams to Fabricate Tough Oil Superabsorbents. Issue 12 (21st September 2018)

• Record Type: Journal Article
• Authors: Ren, Qiang; Dai, Tian; Jin, Xuanyi; Wu, Dun; Wang, Chenyi; Li, Jian; Zhu, Shiping
• Is Part Of: Macromolecular materials and engineering. Volume 303:Issue 12(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-09-21
• Subjects: melamine foam -- oil spill cleanup -- oil superabsorbents -- polyolefin -- toughness; Plastics -- Periodicals; Polymers -- Periodicals; Polymerization -- Periodicals; 547.705
• DOI: 10.1002/mame.201800436
• Languages: English
• ISSNs: 1438-7492

Abstract

Abstract: Oil superabsorbent porous materials having rapid oil/water separation, high oil absorption capacity, good mechanical strength, superior recyclability, low costs, and manufacture scalability are still highly desired for oil spill cleanup applications. In this work, commercially available melamine foams are modified through dip‐coating by polyolefin/toluene solution. All characterizations confirm that polyolefin is successfully coated on surfaces of the melamine foam skeleton, giving a micro‐nano scale hierarchical architecture. The modified foams absorb oil and repel water with a water contact angle higher than 130°. The absorption capacities of the modified foams for various oil and solvents are in the range of 42.6–116.5 g g −1 . The retention of sorption capacity remains above 95% after 100 cycles of sorption–squeezing. Mechanical testing reveals that the compressive‐recovery property is kept and the tensile strains at break of the modified foams are improved compared to their original counterparts. This method is facile, inexpensive, and can be easily scaled‐up. Abstract : Solution processed coating of polyolefin on melamine foams fabricate tough oil superabsorbents. The superabsorbents has absorption capacities for various oil in the range of 42.6–116.5 g g −1, with the sorption capacity retention remaining >95% after 10 cycles of sorption−squeezing. It provides a new and practical approach for the preparation of tough oil superabsorbent materials for oil spill cleanups.