Rhodium‐Catalyzed Mild C7‐Amination of Indolines with Nitrosobenzenes. Issue 47 (18th December 2018)

• Record Type: Journal Article
• Authors: Xiong, Dan; Wang, Lianhui; Jie, Lianghua; Yang, Zi; Li, Lulin; Cui, Xiuling
• Is Part Of: ChemistrySelect. Volume 3:Issue 47(2018)
• Page Start: 13497
• Page End: 13500
• Publication Date: 2018-12-18
• Subjects: amination -- C–H activation -- C–N construction -- indolines -- nitrosobenzenes; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.201803692
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: A mild and practical Rh(III)‐catalyzed C7 –H amination of indolines has been described, which allows the synthesis of a variety of 7‐amino‐substituted indolines with good functional group tolerance and high atom economy. Notably, nitrosobenzenes serve as nitrogen source in this transformation, and therefore behave environmentally friendly for C−N bond constructions. Abstract : An environmentally friendly Rh(III)‐catalyzed C7 –H amination of indolines with nitrosobenzenes has been achieved, which allows the synthesis of a variety of 7‐amino‐substituted indolines with good functional group tolerance and high atom economy.