Conjugated hybrid films based on a new polyoxotitanate monomer. Issue 100 (30th November 2018)

• Record Type: Journal Article
• Authors: Liu, Gang; Yang, Xing; Bonnefont, Antoine; Lv, Yaokang; Chen, Jun; Dan, Wenyan; Chen, Zuofeng; Ruhlmann, Laurent; Wright, Dominic S.; Zhang, Cheng
• Is Part Of: Chemical communications. Volume 54:Issue 100(2018)
• Page Start: 14132
• Page End: 14135
• Publication Date: 2018-11-30
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c8cc07527a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Electropolymerisation of the novel polyoxotitanate (POT ) hexamer [Ti(μ3 -O)(O i Pr)(TA)]6 (TA = thiophene-3-acetate) with 3, 4-ethylenedioxythiophene (EDOT ) gives films of hybrid conjugated copolymer, Poly-(EDOT-POT)s, the morphologies of which are, uniquely, influenced by the electropolymerisation potential. Abstract : Electropolymerisation of the novel polyoxotitanate (POT ) hexamer [Ti(μ3 -O)(O i Pr)(TA)]6 (TA = thiophene-3-acetate) with 3, 4-ethylenedioxythiophene (EDOT ) gives films of hybrid conjugated copolymer, Poly-(EDOT-POT)s, the morphologies of which are, uniquely, influenced by the electropolymerisation potential. NanoporousPoly-(EDOT-POT)-1 is a fast-ion electrode material and has improved electrochromic properties and significantly higher capacitance than that of the parent poly(3, 4-ethylenedioxythiophene) (PEDOT ).