Designing Safe Electrolyte Systems for a High‐Stability Lithium–Sulfur Battery. Issue 10 (17th January 2018)

• Record Type: Journal Article
• Authors: Chen, Wei; Lei, Tianyu; Wu, Chunyang; Deng, Min; Gong, Chuanhui; Hu, Kai; Ma, Yinchang; Dai, Liping; Lv, Weiqiang; He, Weidong; Liu, Xuejun; Xiong, Jie; Yan, Chenglin
• Is Part Of: Advanced energy materials. Volume 8:Issue 10(2018)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2018-01-17
• Subjects: electrolytes -- lithium–sulfur batteries -- safety; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201702348
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract: Safety, nontoxicity, and durability directly determine the applicability of the essential characteristics of the lithium (Li)‐ion battery. Particularly, for the lithium–sulfur battery, due to the low ignition temperature of sulfur, metal lithium as the anode material, and the use of flammable organic electrolytes, addressing security problems is of increased difficulty. In the past few years, two basic electrolyte systems are studied extensively to solve the notorious safety issues. One system is the conventional organic liquid electrolyte, and the other is the inorganic solid‐state or quasi‐solid‐state composite electrolyte. Here, the recent development of engineered liquid electrolytes and design considerations for solid electrolytes in tackling these safety issues are reviewed to ensure the safety of electrolyte systems between sulfur cathode materials and the lithium‐metal anode. Specifically, strategies for designing and modifying liquid electrolytes including introducing gas evolution, flame, aqueous, and dendrite‐free electrolytes are proposed. Moreover, the considerations involving a high‐performance Li + conductor, air‐stable Li + conductors, and stable interface performance between the sulfur cathode and the lithium anode for developing all‐solid‐state electrolytes are discussed. In the end, an outlook for future directions to offer reliable electrolyte systems is presented for the development of commercially viable lithium–sulfur batteries. Abstract : In this review, regarding the design of safe electrolyte systems, the recent development of engineered liquid electrolyte processes is discussed. The design considerations of solid electrolyte in tackling issues for ensuring the safety of electrolyte systems, the future challenges, and research opportunities for offering reliable electrolyte systems for the development of commercially viable lithium–sulfur batteries are also highlighted.